The Museu da Misericórdia is housed in a marvelous 17th-century edifice, this one serving as Brazil’s first hospital. Visits here include a guided tour (in Portuguese) that allows a glimpse of fine period furnishings, portraits and assorted finery dating back four centuries. You’ll also see the attached Igreja da Misericórdia, with its azulejos and a sacristy featuring impressive 18th-century woodwork.